Step one. Install Windows.
Unplug Internet before doing anything. Windows is not trusted and is to be offline only. Double check the LAN is unplugged.
Install Windows on the main drive and try it for a minute. Shutdown. Unplug the main hard drive and plug in the secondary drive.
Plug in the internet and install Linux as normal. Run grub2. quick test and update. Shutdown.
Plug both drives in. From here on, your computer will auto-matically boot into Windows if left alone. If one enters boot options, though (usually f11 during boot screen), one can choose Linux from the list and open Linux normally from there.